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Home Chemistry Chemistry Class 11 Determination of pH for various solutions (e.g. fruit/juices/acids/bases/salts) using pH paper or universal indicator
Chemistry Class 11 Lab Experiments

Determination of pH for various solutions (e.g. fruit/juices/acids/bases/salts) using pH paper or universal indicator



Aim

To determine the pH of various solutions (fruit juices, acids, bases, and salts) using pH paper or universal indicator solution and verify the results through systematic laboratory experimentation.

Introduction

pH determination is a fundamental analytical technique in chemistry that measures the hydrogen ion concentration in aqueous solutions. This experiment helps students understand the acidic, basic, or neutral nature of different substances commonly encountered in daily life and laboratory settings.

Apparatus Required

Equipment:

  • pH paper strips (various ranges)
  • Universal indicator solution
  • Glass rods or stirring rods
  • Test tubes (10-15 pieces)
  • Test tube stand
  • Droppers (5-7 pieces)
  • Measuring cylinder (50ml)
  • Beakers (100ml, 250ml)

Chemicals:

  • Distilled water
  • Lemon juice
  • Orange juice
  • Vinegar (acetic acid)
  • Dilute HCl solution
  • Dilute NaOH solution
  • Ammonia solution
  • Sodium chloride solution
  • Sodium carbonate solution
  • Ammonium chloride solution

Theory

pH Concept

pH is defined as the negative logarithm of hydrogen ion concentration: pH = -log[H⁺]

pH Scale:

  • 0-6: Acidic solutions
  • 7: Neutral solutions
  • 8-14: Basic/Alkaline solutions

Indicators

Indicators are organic compounds that change color at specific pH values:

  • pH paper: Pre-prepared strips with different indicators
  • Universal indicator: Mixture of several indicators showing various colors across pH range

Common pH Values:

  • Lemon juice: 2.0-2.6 (Highly acidic)
  • Orange juice: 3.3-4.2 (Acidic)
  • Vinegar: 2.4-3.4 (Acidic)
  • Distilled water: 7.0 (Neutral)
  • Soap solution: 9-10 (Basic)

Procedure

Method 1: Using pH Paper

  1. Preparation: Clean all apparatus with distilled water and arrange test tubes in the stand

  2. Sample Collection: Take 10ml of each solution in separate test tubes

  3. pH Paper Application:

    • Take a strip of pH paper
    • Dip one end of the strip into the solution for 2-3 seconds
    • Remove and shake off excess liquid gently
    • Wait for 10-15 seconds for color development
  4. Color Comparison:

    • Compare the color with the standard pH chart
    • Note down the corresponding pH value
  5. Repeat Process: Perform the test for each solution

Method 2: Using Universal Indicator

  1. Preparation: Take 5ml of each solution in separate test tubes

  2. Indicator Addition: Add 2-3 drops of universal indicator to each test tube

  3. Color Observation: Observe the color change in each solution

  4. pH Determination: Match the color with the universal indicator chart

  5. Recording: Note down the pH values for all solutions

Observation Table

S.No. Solution Color with pH Paper pH Value Color with Universal Indicator pH Value
1 Distilled Water Green 7 Green 7
2 Lemon Juice Red 2 Red 2
3 Orange Juice Orange 3 Orange-Red 3
4 Vinegar Red-Orange 3 Red-Orange 3
5 Dilute HCl Red 1 Red 1
6 Dilute NaOH Dark Blue 12 Purple 12
7 Ammonia Solution Blue 11 Blue 11
8 Sodium Chloride Green 7 Green 7
9 Sodium Carbonate Blue-Green 9 Blue-Green 9
10 Ammonium Chloride Yellow-Orange 5 Yellow-Orange 5

Result

The pH of various solutions was successfully determined using both pH paper and universal indicator methods:

  • Highly Acidic Solutions (pH 1-3): HCl, Lemon juice, Vinegar
  • Weakly Acidic Solutions (pH 4-6): Orange juice, Ammonium chloride
  • Neutral Solutions (pH 7): Distilled water, Sodium chloride
  • Weakly Basic Solutions (pH 8-10): Sodium carbonate
  • Highly Basic Solutions (pH 11-14): NaOH, Ammonia solution

Both methods provided consistent results, validating the accuracy of pH determination techniques.

Precautions

  1. Handle chemicals carefully: Use gloves and safety goggles when handling acids and bases

  2. Use fresh indicators: Expired pH papers may give inaccurate readings

  3. Clean apparatus: Ensure all test tubes are thoroughly cleaned to avoid cross-contamination

  4. Proper dipping technique: Avoid prolonged contact of pH paper with solutions

  5. Lighting conditions: Compare colors under uniform lighting conditions

  6. Store properly: Keep pH papers in airtight containers to prevent moisture damage

  7. Dispose safely: Follow proper disposal procedures for chemical waste

  8. Multiple readings: Take at least two readings for each solution to ensure accuracy

Viva Voce Questions and Answers

Q1: What is the principle behind pH determination using indicators?

A: Indicators are weak organic acids or bases that change color depending on the hydrogen ion concentration. The molecular structure changes with pH, altering the color observed.

Q2: Why is universal indicator more useful than individual indicators?

A: Universal indicator provides a wide range of colors across the entire pH scale (0-14), allowing determination of approximate pH values, whereas individual indicators change color over a narrow pH range.

Q3: What happens to pH paper in acidic solutions?

A: In acidic solutions, pH paper typically shows red, orange, or yellow colors depending on the strength of acidity.

Q4: How do you interpret a green color on pH paper?

A: Green color indicates a neutral solution with pH around 7, like distilled water or neutral salt solutions.

Q5: Why do salt solutions have different pH values?

A: Salt solutions can be acidic, basic, or neutral depending on the strength of the acid and base from which they are formed:

  • Strong acid + Strong base = Neutral salt
  • Weak acid + Strong base = Basic salt
  • Strong acid + Weak base = Acidic salt

Q6: What precautions should be taken while using pH paper?

A:

  • Don't dip the entire strip in solution
  • Compare colors immediately after removal
  • Use fresh strips for each test
  • Keep away from moisture and direct sunlight

Q7: Can pH be negative or greater than 14?

A: Yes, very concentrated acids can have negative pH values, and very concentrated bases can have pH values above 14.

Q8: What is the significance of determining pH in daily life?

A: pH determination is crucial in:

  • Agriculture (soil pH affects plant growth)
  • Medicine (blood pH maintenance)
  • Food industry (preservation and taste)
  • Environmental monitoring (water quality)
  • Personal care products (skin compatibility)

Conclusion

This experiment successfully demonstrated the determination of pH for various solutions using pH paper and universal indicators. Students gained practical experience in:

  • Understanding acid-base behavior of different substances
  • Using analytical techniques for quantitative measurements
  • Interpreting color changes in indicator systems
  • Applying theoretical knowledge to practical scenarios

The consistent results obtained from both methods validate the reliability of these simple yet effective analytical techniques for pH measurement in laboratory settings.